Determination of 17 kinds of banned organochlorine pesticides in water by activated carbon fiber-solid phase microextraction coupled with GC-MS.

Activated carbon fiber (ACF) as extraction fiber for solid-phase microextraction (SPME) and its application for the analysis of banned organochlorine pesticides (OCPs) were investigated. Firstly, ACF was activated by different concentration of zinc chloride, which indicated that ACF activated by 60% zinc chloride had a reasonable specific surface area, pore volume and pore distribution. Secondly, the parameters for the ACF-SPME procedure, the adsorption and desorption conditions, were also optimized when coupled with gas chromatography-mass spectrometry (GC-MS). Thirdly, the ACF-SPME was used to analyze 17 kinds of OCPs in water. The linearity of most pesticides was found to be between 0.2 and 50 microg/l with GC-MS under the selected ion monitoring (SIM) acquisition mode. The limits of detection (LOD) at the sub microg/l were obtained. The work demonstrated here shows that ACF is a promising alternative for the SPME procedure.     

Weak and Strong Solutions for the Stokes Approximation of Non-homogeneous Incompressible Navier-Stokes Equations

In this paper,the Dirichlet problem of Stokes approximate of non-homogeneous incompressibleNavier-Stokes equations is studied.It is shown that there exist global weak solutions as well as global andunique strong solution for this problem,under the assumption that initial density ρ_0(x)is bounded away from0 and other appropriate assumptions(see Theorem 1 and Theorem 2).The semi-Galerkin method is applied toconstruct the approximate solutions and a prior estimates are made to elaborate upon the compactness of theapproximate solutions.     

Semilinear Differential Inclusions in Separable Banach Spaces

Ｓｅｍｉｌｉｎｅａｒ　Ｄｉｆｆｅｒｅｎｔｉａｌ　Ｉｎｃｌｕｓｉｏｎｓ　ｉｎ　Ｓｅｐａｒａｂｌｅ　Ｂａｎａｃｈ　ＳｐａｃｅｓＸｕｅＸｉｎｇｍｅｉ（薛星美）ａｎｄＳｏｎｇＧｕｏｚｈｕ（宋国柱）（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｈｅｍａｔｉｃｓ，Ｎａｎｊｉｎ...     

Synthesis and Structural Characterization of Adduct [La(NO_3)_3·4H_2O]·2(BQEB)

Differentkindsofopenchaincrownethershavebeensynthesizedasthemodelcompoundsofionophoresandtheirinteractionswithsodium,potassiumandrareearthionshavealsobeenstudiedl'z.PanshowedCe(III)yieldedalf1complexwithl,8-bis(8'-quinolyloxy)-3,6-dioxaandtheCe(IIl)ioncoordinatedbothtoetheroxygenandquinolinenitrogenatoms3.TUmInleridentifiedtwolanthanidenitratecomplexeshavingastoichiometryof3:2(3RE:2L)'.InordertostUdythefunctionsofbothquinolineandbenzenering,introducedintothepolyetherchain,a1inearpolyether…     

The measurements of correlation times of molecules adsorbed on silica gel,alumina and charcoal using NOESY and MAS NMR

The correlation times (τ_c) and cross relaxation rates of toluene, dimethylformamide, tetrahydrofuran, water-acetone and water-dioxane adsorbed on silica gel, alumina and charcoal were obtained by measurements of the integrated intensities of cross and diagonal peaks in their NOESY spectra. The (τ_c) of the above mentioned systems is in the range of 10^?6?10^?9 s, much longer than that in the liquid (10^?12?10^?14 s). It was found that intramolecular rotation of toluene adsorbed on charcoal is slower than that on SiO₂, Al₂O₃ and the inversion of α and β protons in tetrahydrofuran is very fast (τ_c = 1.76×10^?9 s). The cross relaxation plays an important role in the relaxation of molecules adsorbed on solid surfaces with low electron densities.     

纳米二氧化锆制备过程的DSC、TGA和XRD研究

用ＤＳＣ、ＴＧＡ和ＸＲＤ技术研究了在沉淀法制备纳米ＺｒＯ２的过程中，残留ＮＨ４Ｃｌ、ｐＨ值、滴加方式、以及结构稳定剂Ｙ２Ｏ３的添加量对结晶过程的影响。结果表明，残留ＮＨ４Ｃｌ使结晶化温度降低，使放热过程变为吸热过程。而ｐＨ值、滴加方式和结构稳定剂的添加对结晶过程无明显影响。     

活性炭酸处理对CuO／C催化剂上NO还原反应的影响

４种国产活性炭被用于ＮＯ还原反应，其中，山楂核炭和山桃核炭具有较高的ＮＯ还原转化率。实验发现，表面含氧基团－ＣＯＯ－对活性炭自身的还原性和对ＮＯ的还原活性有很重要的影响。对表面富－ＣＯＯ－基团的活性炭，稀盐酸处理使表面－ＣＯＯ－显著分解。